Hi folks, I have had the same problem here is the info:
2001 Alhambra 1.9 AUY engine 165,000 miles
Intermittent overheating after long journeys (5 hours+)
No oil loss or cross contamination.
Coolant generally clean but not perfect.
After overheating the expansion tank full of coolant and volcano's air through it when opening signifying a lot of pressure in the system.
Loss of heat in the cabin shortly before the overheating of the coolant.
What I have done so far;
Water pump replaced (pump found to be detached from spindle!)
6 months later it happened again,
Thermostat replaced (old thermostat caked in crap but tested and worked fine)
3 months later it happened again,
opened expansion tank, lots of air through but started working fine again!
2 months later its happened again after about 6 hours of driving, coolant temp rising oil temp not so bad.
Normally it stops but not this time, flushed the coolant system to find a lot of crap (rust like deposits).
Having convinced myself it is a cracked cylinder/head gasket I tried using "steel seal" following the instructions to the letter, I then had a 150 mile return trip and it overheated again. I could go into details about my thoughts on the product but I'm on the fence!
After that trip having googled the problem to pieces I removed the return pipe and flushed it through with a hose after finding it was not fully clear (there was a small flow),
Now the car is running fine, I'm not sure what has cured it but I would recommend both, either it was the return pipe or the steel seal, thanks to Pete (hull) for the detailed info!
Jimbobmelad, December 2013