I had a similar problem on a job last year.Took me ages to find a cure.Eventually I fitted a new expansion vessel and I haven`t been called back in over 8 months.
It`s a strange fault,because it appears to be a leak yet there is no sign of water.I can only think that the diaphragm in the expansion vessel is perforated and slowly lets water through which mimics a loss of pressure.
If the vessel is awkward to get at,just fit a new round vessel somewhere else on the system,it`ll do the same job.
Gasman, August 2008