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Burnner won't come on after 20minute of first ignition.pilot light come on?

Got netheat 50 opern vent pumpsysterm boiler.
When u on the boiler first time it will igniteproperly.
But after 15 to 20 minute it's go off .
Pilot light come on but not burnner won't come on.
Joe, December 2011
could be the thermocouple

mm, December 2011