Similar to some of the other stories here, my Aqualisa Aquarian thermostatic shower was leaking. To be more specific, despite being off, it started as a drip through the shower head, then after a few weeks became more constant.
I removed the outer covers and the on/off knob. This gave me access to remove the flow control spigot (on left hand side in my shower). To remove the spigot you need to remove the threaded retaining ring, then pull it out. On the spigot itself, you should be able to see the 3 O-rings on the thin section, and another larger one on the larger section that mates with the cartridge body. On my one, I found that the o-ring at the point of the spigot had been sheared flat on the outer circumference - inside the cartridge it appears to seal against the internal surface of a metalic cone with holes in it, you can see this by looking in through the port that supplies the shower head.
Once I had obtained a replacement o-ring (circa 10p), it was a simple job to grease, and fit to the spigot. It was a bit more trial and error to refit the spigot in to the cartridge properly. Firstly, the thin part of the spigot is connected to the wider part by a wide thread - this acts as a "worm drive" to push the spigot in and out, thus opening and closing the seal. It appears that this threaded section needs to be exposed a bit to allow for the stroke in and out. Secondly, on the thin part of the spigot, roughly half way along there's a "cross". Now if you have a look at the end of the cartridge body where the spigot goes in, you will see some recessed "runners" on either side. The cross section has to fit in to the runners - there's a specific shape to the cross/recepticle that will only allow it to go in with a specific orientation.
It took a few goes before I'd sussed this out, but worth it the end.
Ronzer, October 2009