Eventually got to the bottom of this so thought I'd do an update.
Boiler started cycling not on just hot water but on heating too so had the main circuit board replaced( this is the second time one has gone). The combi specialist also replaced the heat exchanger ( this was well bunged up). Surprisingly he did not replace the Pressure Release valve which started to leak quite badly, especially after he emptied the system through it to do the Heat Exchanger. However bought this myself, (a word of warning whilst it is possible just to change the internal springs and seals, if it has been leaking some time the surfaces can be quite corroded) so I replaced the whole thing, details how to are in the manual. Result all is working as it should, system holds pressure so now putting in cleanser for a few weeks then draining and then leak suppressant/additive as all the topping up adds air to the system which aids corrosion and helps sludge form.
The expansion vessel is fine, does not leak, so all in all a result although it would almost have been cheaper to buy a new boiler, the combi specialist charged £350 but when your heating goes on Christmas Eve...!
Thanks for all the suggestions and advice
Keith Barclay, January 2009