Hi,
Is there water leaking from your boiler overflow outside?
If so, it is because this red 3 bar valve, is a safety valve and should not be used to drain water from a boiler, what can happen is some dirt gets trapped under the seat of the valve and then it weaps forever.
You can drain your boiler (from its drain point, see manual) and then remove the 3bar valve, take it apart and clean it.
But, you also say your boiler pressure got to 4bar! the safety valve should lift at 3bar (hence the name!)
If your boiler pressure is climbing this high all the time when in use sounds like the pressure vessel may be shot
Tony, February 2008