The pressure release valve only blows off at or above 3bar pressure.
Check what is your pressure when system is totally cold (should be 1 - 1.5 bar) if it is above this bleed some water from
one of your radiators until at 1 bar, then all should be fine.
If it already reads 1 - 1.5 bar, but when heating system is on rises to above 3 bar then the expansion vessel in you system may either need recharging or replacing.
T, March 2008