Firstly,put tyre pressure gauge on the expansion vessel should be .5bar If it is not, does water come out, if it does pressure vessel propably faulty, but its far more likely to be heat exchanger had problems when the boilers have been fitted without limescale filters.To proove it turn off water supply to boiler, reset boiler pressure to 1.5bar (cold).Turn on heating if its leetching through to the heat exchanger the pressure should not rise to the same extent,it will of course rise since your heating water but not to same pressure. Replace heat exchanger
P Creed Plumbing & Heating, December 2009