the problem maybe that with the pressure too high the filling loop may be passing. release some pressure from the central heating system back down to 1 bar, and then check when heating is on if pressure rises over 3 bar, it maybe that you vessel has gone, this can be sorted by fitting a remote vessel near to the boiler, as sometimes the boiler has to be removed off of the wall to replace the old vessel!
jb, c&j plumbing&heating sheffield, May 2009