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My valiant VC GB 110 H boiler wont stay ignited?

My valiant VC GB 110 H boiler wont stay ignited. At first it went out for no reason. Now when i relight the pilot it wont stay on. What would cause this? The pilot just wont hold once lit, even after a minute of holding it alight.
Chris, March 2009
Usually, a thermocouple that is defective will cause this.

Chino, March 2009