I suspect that you will have problems...
Here's an excellent compatibility list from Invensys that gives pin-out lists...
http://www.heatweb.com/pdf/Invensys/Programmer%20Compatibility%20Chary.pdf
It shows both 102 & 103 having Neutral and Live on connectors 5 & 6 respectively but there the similarity ends
102 1 = H/W 0n - 2 = C/H On
103 1 = On - 2 = Spare - 3 = Common
They describe the 102 as a Programmer and the 103 as a Timeswitch.
Good luck...
Peccavi, April 2009