My Daughter's '99 206 does it too. Seems to run very very rich, sometimes floods, then sometimes will rev like crazy for no reason. I think it might be the oxygen sensor and will try a new one. Looks like a very common problem, but no one seems to be able to offer an answer. It's a very dangerous fault, so I've pulled the plug out of the stepper motor to stop it revving randomly. This will cause cold driving problems though.
Oily Paul, September 2010