Your heating system needs balancing...that is, some of the lockshield valves on the radiators need to be closed down a bit, so that the hot water is forced to go around the radiators that usually remain cool. Try turning the lockshield valves fully off, and then open again 3/4 of a turn, and see what happens. Keep all TRV's open full and set the circulating pump to position 3 if its adjustable.
John, November 2009