Got home last night and the gurgling sound from the boiler was a giveaway. Condensate drain was blocked. As you say, Eddie, I assume the drain is frozen (probably where it goes through the wall into the external rainwater down-pipe). For now, I've removed the pipe from the bottom of the boiler and placed a bucket underneath. I'll wait for the weather to warm up before refitting. I can't see how to prevent this from happening in the future but, fortunately, we dont usually get weather as cold as we have had it for the past week or so (U.K. 8 Jan 2010)
Ian, January 2010