A way to check if the expansion vessel is okay.
Pressurize to boiler to 1 bar and turn on the heating, as the boiler warms up the guage shouldn't raise above 1.5 bar (This also is dependent on system size).
If you find it rising up to 2.5 - 3 bar as the heating gets hotter, it would indicate that the expansion vessel would need recharging, if that is the case, it explains where the pressure is going, out through the prv.
Carefree, August 2010