You have more than one problem, the F75 is one of three things:
Low water pressure:
Faulty pressure sensor:
or Faulty pump:
(see the response to 'vaillant boiler' 5 questions below your question).
The issue with radiators coming on is a little more in depth. Basically, it's a diverter valve or pcb issue.
If there is a C in the display, the water pre-heat is on, the boiler tries to heat up the domestic heat exchanger, but due to diverter valve being in the wrong position (or passing), the heat generated is sent around the radiators, it keeps going because the DHE never gets satisfied.
As a temporary cure, turn off the preheat (C ) in the display, this involves turning the top left dial (HW) all the way down to the left (minimum), the C in the display will disappear, you can now turn the dial back up to a reasonable position, this will stop the radiators constantly heating up, however, they will still heat up when you run any hot tap until you get the diverter valve/pcb issue resolved.
Carefree, January 2011