Try checking ALL joints to the radiator from the point it was teed into the system.
A possible alternative to a leak could be an expansion vessel problem, the extra litreage added by the new radiator could be enough to push a failing vessel to the point where it fails.
Turn on your heating, as it warms up, check the pressure guage on the boiler, it it rises close to, or up past the red section, it could be be the expansion vessel discharging water through the pressure relief valve, giving the same effect as having a leak.
Carefree, February 2011