the boiler will have a one way valve beneath the central heating pump..small plastic disc.
these can become stuck 'open' by a pece of solder, dirt etc, and cause the heat store for the hot water to bypass into the central heating circuit.
seen it often.
also, you do not need the boiler 'on' 24/7, get an engineer who knows his job to set your DHW timer for an 'off' period between, say, 00.00 to 06.00, to avoid night time cycles.
mark properjob, February 2012