your system is pumping over. which is where the boiler heats the water and rising up the vent pipe into the header tank. check your pump is working . check the speed of your pump. or most common you have a block in the pipe feeding the system from the header tank. it useally blocks where the pipe from header tank tees into the system pipe work corrosion clogs and blocks the pipe .if its that bad you can sometimes find the block by running a magnet down the pipe where it joins the system and see if it sticks. if it stick thats where the rust blockage is. or drain your system down and see if the header tank ballvalve starts to refill if it don't you no the water in not getting through the block. also see if the tank is got alot of silt in the bottom.
hi-spec plumbing, October 2006