SAlly.
My guess is that the moisture is condensation. You have a nice insulated door and the wall is a cavity wall - hopefully insulated - but the wall round the door frame is brick or block, from inside to out, where the cavity comes to an end.
Often this acts like a "cold bridge", making the bit of wall round the window or door cool enough for the moisture in the air to condense.
The solution is to reduce the moisture in the air, if you can and/or to add ventilation, preferably with heat recovery and/or add insulation round the door opening, if you can.
here's some ideas:
http://www.envirovent.com/home-ventilation/products/heat-recovery-systems/heatsava/
http://www.i-sells.co.uk/eclipse-heat-recovery-ventilator-bm3012?gclid=COOdnoux-MMCFcXLtAoduRgAjQ
X, February 2015