Why not do a simple google search for the manual, for starters?
http://heatingsparesltd.com/download/boiler_manuals/Protherm/40-50_CI_User_Installation_and_Servicing_Instructions.pdf
The boiler itself can do pumped heating and gravity hot water.
The boiler can also do pumped heating and pumped hot water, using a diverter valve.
In either case, the heating and hot water would normally be controlled by a timeswitch (aka programmer or controller), so find that and download a manual (Google search)
XXX, August 2016