Angie (and anyone else happening upon this site) -
I also had the F.22 error on my Vaillant ecoTEC combi boiler. I looked underneath and found two valves. I turned one, then the other, but nothing happened.
Happily, on another HowToMendIt thread, someone said to open the left valve, then the right one *while the left valve was still open*. (Left and right are per one being underneath the boiler with one's head to the wall.)
That was the answer to my problem. Now, if I could only answer the problem of my boiler installer's mobile phone number being no longer available 7 months after installation ...
Shazzbot, July 2011