from the info you've given i'd say either theres no air in the expansion vessell, the expansion vessel has a hole in the diaphragm or theres a blockage in the pipe that goes to the expansion vessel, either way your gonna need a new pressure relief valve cos once they go off they dont generally close properly causing them to leak even after the fault has been remedied!
ignore the other comment! we cant all know everything about heating systems or their names!
KAW!, September 2007