Try Re-charging the pressure Vessel with a car tyre pump through the valve on the top of the unit, (usually right under the fue pipe)it should be between 0.75 and 1 bar. If it does not hold pressure then you will have to replace it. You can add another expansion vessel to the central heating return pipe (as near to the boiler as possible), this does not involve removing the boiler from the wall, but it does depend on the location of your boiler and the amount of accessible space below it.
if you're not good with pipework then get a plumber.
Phil, April 2007