Sounds like the diaphram on the expansion chamber may have gone. You can tell if there is water at the air valve. I drained a small unused rad and reconnected it without bleeding. The air trapped inside will act as an expansion cushion. You will need a new exp. chamber, but this does not have to be fitted to the boiler. If it is, the boiler has to come off the wall.
John Dickens, October 2010