Hi, i am having the same problem but i know where the valve you are looking for is...its to the rear of the 100E...you need to remove the left side cover off the boiler...(control panel, burner cover/window need to be moved first), and you will see a large red plate size tank with a bike tire like valve on the top left...Pump this up to 11.6 psi, you will have to slightly over pressurize it as when you take the valve off you will lose some pressure....i have done all this but have no hot water and low heating so i think i need a PCB.....NICE.....
Hope that helped you....
Paul Roberts, March 2013