Just in case you're still struggling with this, and for other people looking to solve the same problem.
Having just had one of these units installed with a new boiler, I've finally figured it. The unit has two temperature settings that the pathetic instructions call, 'Comfort' and 'Setback'. These two temps can be set using the slider on the right to select the relevant symbol: spin the knob until the desired temperature is shown. Set the comfort setting to the temp you want during the 'On' periods. During the 'Off' periods the system will still be active and call for heat (turn the boiler on) if the temp drops below the 'Setback' setting.
So set the comfort setting to the temperature you want say 19C and set the setback temp to the absolute minimum you want it to get say 10C. In summary then it's not so much of an off and on system as we've come to know from the old Mechanical timers but rather an 'On warm' and 'On cool' system. If you want the system to go totally off I think the only way would be to turn off the heating at the boiler manually. You can always turn the 'setback' setting right down to the min (5C I think).
Chris., December 2010