From brief explained symptoms, I would say the hot water divertor is faulty. This is a component that reconizes you are running hot water. However, if diaphram split your boiler will not fire for hot water. This is a cheap part to buy approx £11.00.
An engineer should be able to complete this repair no more than two hours.
Rob, RJS Heating Ltd www.rjsheating.co.uk, August 2009