hi its unlikely that the HW is leaking into the CH , this would require two damaged pipes and a leap across a gap. ,so unless someone has recently been altering your pipe work ,its more likley to be the filling loop , this is something close to the boiler , probably a braded hose with an inline tap , which should be off. it should also have a nut to disconnect it comletly, but if you take it off to check, do it with the mains water off, only other thing is could you be confusing the natural increas in preasure that happens when the CH goes up in temprature , usualy to a max 3 bar.
warren, November 2009