I presume you are talking about the expansion vessel...
You need to drain the boiler and pump the expansion vessel up to 1 Bar... You need to do this with a foot pump with it's own gauge... You do not want the boiler to register anything whilst pumping up the vessel, once at a bar... You then need to reconnect the boiler and fill the system to 1bar as shown by the boiler with water.
GasAid.co.uk, December 2006