I can only add a comment about this same Glow worm boiler model (Compact 100e) which we inherited as we moved into this house last April 2007. It is only 7 yrs old and works well since having a split rubber diaphagm replaced on the (I think) Diverter valve. But there seems to be no means of adjusting the water output temperature. It is just too hot for comfort yet try as I might to find the info in the 44pp Instruction book for this seemingly basic adjustment I've found nothing on the subject! Sorry not to help with your cold starting problem.
Frank Millington, Croydon.
Frank Millington, November 2007