its poss the pump is faulty. it sounds like the pump is running but may be worn and not circulating the water as quick as it should.
on the side of the pump is a switch with three speed try upping it a speed.
also as mentioned try a descaler kettling is due to cold droplets of water dropping on to a hot heat exchanger.
i always use the sentinel x200 boiler noise reducer, put it into system and leave it it doesn't have to be drained out and you can still add an inhibitor.
try this site tell you all you need to know.
http://www.sentinel-solutions.net/en/
plus not knowing how old your system is or what boiler you have.
hi-spec plumbing, June 2007